Synthesis of Medium-Sized Cycloalkenes via Fused-Cyclobutenes (Springer Theses) free ebook download.

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Synthesis of Medium-Sized Cycloalkenes via Fused-Cyclobutenes (Springer Theses) free ebook download

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Author(s):	Tomohiro Ito

Date:	2024	Format:	rar	Language:	English	ISBN/ASIN:	9819707862
Pages:	141	OCR:		Quality:		ISBN13:
Uploader:	alex21s	Upload Date:	6/21/2024 7:05:27 PM

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9819707862 rar
This book explains the existence of the intermediate using two approaches: computational chemistry and coordination chemistry. In this book, the author has developed new methods for synthesizing medium-sized cycloalkenes by utilizing the 4-electrocyclic reaction of fused-cyclobutenes. The fundamental and most important strategy and feature of the work are as follows: first, cyclobutene is used as a readily available raw material with high-strain energy to generate more strained medium-sized cis,trans-cycloalkadiene molecules. Second, by judiciously selecting the reaction conditions, the short-lived intermediate (medium-sized cis,trans-cycloalkadiene) can be converted to medium-sized cis- or trans-cycloalkenes. For the former, the generation of the medium-sized cis,trans-cycloalkadiene intermediate is greatly affected by the substituent on the cyclobutene, and there are few examples of its generation confirmed at room temperature. Regarding the latter, the synthesis of

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Tags: Cycloalkenes Fused-Cyclobutenes Medium-Sized Springer Synthesis Theses

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