Photochemical and Electrochemical Activation Strategies of C(sp3)-Based Building Blocks for Organic Synthesis (Springer Theses) free ebook download.

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Photochemical and Electrochemical Activation Strategies of C(sp3)-Based Building Blocks for Organic Synthesis (Springer Theses) free ebook download

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Author(s):	Su Yong Go

Date:	2024	Format:	pdf	Language:	English	ISBN/ASIN:	9819989930
Pages:	196	OCR:		Quality:		ISBN13:
Uploader:	gestalt	Upload Date:	4/10/2024 2:51:39 AM

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9819989930 pdf
This book addresses novel C(sp3)-C(sp2) and C(sp3)-heteroatom bond-forming reactions. Two strategies are given in the book using photoredox or electrochemical methods. The first strategy describes that the hydroalkylation of alkynes via photoredox-mediated Ni/Ir dual catalysis produces trisubstituted alkenes as versatile synthetic building blocks for the synthesis of pharmaceutical agents and natural products. High regioselectivity and E/Z-selectivity were achieved by introducing silyl groups that can provide steric and electronic effects to these selectivities with extensive opportunities for post-functionalization.
The second strategy enables the development of C(sp3)-heteroatom bond-forming reactions through the electrochemical activation of C(sp3)-B bonds. The bonding of heteroatoms to carbon atoms has been an enduring subject of investigation for organic chemists. The function of most molecules is mainly determined by heteroatoms attached to the carbon atom, althoughthe backbone structure of organic compounds comprises carbon fragments.
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Tags: Activation Blocks Building Csp3-Based Electrochemical Organic Photochemical Springer Strategies Synthesis

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