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Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles free ebook download

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Chemistry

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Author(s):	Hyung Yoon

Date:	2020	Format:	PDF,EPUB	Language:	English	ISBN/ASIN:	3030540766
Pages:	1	OCR:		Quality:		ISBN13:
Uploader:	gestalt	Upload Date:	9/3/2020 8:50:44 PM

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This book presents Pd- and Ni-catalyzed transformations generating functionalized heterocycles. Transition metal catalysis is at the forefront of synthetic organic chemistry since it offers new and powerful methods to forge carboncarbon bonds in high atom- and step-economy.
In Chapter 1, the author describes a Pd- and Ni-catalyzed cycloisomerization of aryl iodides to alkyl iodides, known as carboiodination. In the context of the Pd-catalyzed variant, the chapter explores the production of enantioenriched carboxamides through diastereoselective Pd-catalyzed carboiodination. It then discusses Ni-catalyzed reactions to generate oxindoles and an enantioselective variant employing a dual ligand system.

Chapter 2 introduces readers to a Pd-catalyzed diastereoselective anion-capture cascade. It also examines diastereoselective Pd-catalyzed aryl cyanation to synthesize alkyl nitriles, a method that generates high yields of borylated chromans as a single diastereomer, and highlights its synthetic utility.

Lastly, Chapter 3 presents a Pd-catalyzed domino process harnessing carbopalladation, CH activation and -system insertion (benzynes and alkynes) to generate spirocycles. It also describes the mechanistic studies performed on these reactions.
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	Title	Link	Password	Size (MB)	Thank to	Inform Admin
2857940	Book	https://k2s.cc/file/bcb5d56f3bb2b...		16.28	gestalt
2857941	Book	https://k2s.cc/file/9fffc0401c309...		36.51	gestalt

Tags: Catalyzed Forming Functionalized Heterocycles Nickel Palladium Transformations

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Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles free ebook download

Category: Chemistry

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Category:
Chemistry