Organomagnesium Methods in Organic Synthesis (Best Synthetic Methods) free ebook download.

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Organomagnesium Methods in Organic Synthesis (Best Synthetic Methods) free ebook download

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Chemistry

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Author(s):	Basil J. Wakefield

Date:	1995-04-26	Format:	pdf	Language:	English	ISBN/ASIN:	0127309454
Pages:	1	OCR:		Quality:		ISBN13:
Uploader:	tvladb77	Upload Date:	1/14/2021 10:49:10 PM

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The book opens with a general overview of the constitution and reactivity of organomagnesium compounds, followed by information on handling them and on their detection and estimation. Throughout, practical aspects aswell as principles are emphasized.

The chapters on the synthesis of organomagnesium compounds cover the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes, as well as the traditional preparation of Grignard reagents. Preparations by metallation and metal-halogen exchanges are also included, as are newer methods such as hydromagnesiation of alkenes and alkynes.

Systematic coverage is provided on synthetically useful reactions of organomagnesium compounds. Of fundamental importance in organic synthesis are carbon-carbon bond forming reactions  additions to carbon-carbon, carbon-nitrogen, carbon-oxygen, and carbon-sulfur multiple bonds  and nucleophilic substitution at carbon. The formation of carbon-heteroatom bonds in organic compounds is described, where the heteroatom is hydrogen, nitrogen, oxygen, sulfur, or halogen. Finally, the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds is outlined.

Representative experimental procedures are included throughout the book, and tables with references to well-described examples are provided.

Presents a general overview of the constitution and reactivity of organomagnesium compounds
    Provides coverage on the detection and estimation of organomagnesium compounds
    Emphasizes practical aspects as well as principles
    Covers the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes
    Includes preparations by metallation and metal-halogen exchanges
    Reviews new preparation methods such as hydromagnesiation of alkenes and alkynes
    Outlines information on synthetically useful reactions of organomagnesium compounds
    Describes the formation of carbon-heteroatom bonds in organic compounds
    Addresses the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds
    Includes representative procedures and tables with references to well-described examples

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Tags: Best Methods Organic Organomagnesium Synthesis Synthetic

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