Highly Luminescent Lanthanide Complexes with Specific Coordination Structures. free ebook download.

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Highly Luminescent Lanthanide Complexes with Specific Coordination Structures. free ebook download

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Chemistry

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Author(s):	Kohei Miyata

Date:	2014	Format:	PDF	Language:	English	ISBN/ASIN:	4431549439
Pages:	1	OCR:		Quality:		ISBN13:
Uploader:	topron	Upload Date:	7/13/2019 10:49:55 PM

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This thesis deals with strongly luminescent lanthanide complexes having novel coordination structures. Luminescent lanthanide complexes are promising candidates as active materials for EL devices, lasers, and bio-sensing applications. The organic ligands in lanthanide complexes control geometrical and vibrational frequency structures that are closely related to the luminescent properties. In most of the previous work, however, lanthanide complexes have high-vibrational frequency CH units close to the metal center for radiationless transition. In this thesis, the luminescent properties of lanthanide complexes with low-vibrational frequency CF and P=O units are elucidated in terms of geometrical, vibrational, and chemical structures. The author also describes lanthanide coordination polymers with both high thermal stability (decomposition point &gt  300C) and strong-luminescent properties (emission quantum yield &gt  80%). The author believes that novel studies on the characteristic structures and photophysical properties of lanthanide complexes may open up a frontier field in photophysical, coordination and material chemistry.

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Tags: Complexes Coordination Highly Lanthanide Luminescent Specific Structures

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