Molecular Orbitals of Transition Metal Complexes free ebook download.

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Molecular Orbitals of Transition Metal Complexes free ebook download

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Chemistry

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Author(s):	Yves Jean

Date:	2021	Format:	rar	Language:	English	ISBN/ASIN:	0198530935
Pages:	263	OCR:		Quality:		ISBN13:
Uploader:	eternal	Upload Date:	8/13/2021 4:49:51 AM

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This book starts with the most elementary ideas of molecular orbital theory and leads the reader progressively to an understanding of the electronic structure, geometry and, in some cases, reactivity of transition metal complexes. The qualitative orbital approach, based on simple notions such
as symmetry, overlap and electronegativity, is the focus of the presentation and a substantial part of the book is associated with the mechanics of the assembly of molecular orbital diagrams. The first chapter recalls the basis for electron counting in transition metal complexes. The main ligand
fields (octahedral, square planar, tetrahedral, etc.) are studied in the second chapter (sigma interactions) and the structure of the "d block" is used to trace the relationships between the electronic structure and the geometry of the complexes. The third chapter studies the change in analysis when
the ligands have pi-type interactions with the metal. All these ideas are then used in the fourth chapter to study a series of selected applications of varying complexity (structure, reactivity). The fifth chapter deals with the "isolobal analogy" which points out the resemblance between the
molecular orbitals of inorganic and organic species and provides a bridge between these two subfields of chemistry. The last chapter is devoted to a presentation of basic Group Theory with applications to some of the complexes studied in the earlier chapters.

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Tags: Complexes Metal Molecular Orbitals Transition

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